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This International Standard specifies a potentiometric Karl Fischer titration method for the direct determination of water in crude petroleum. It covers the range 0,05 % (m/m) to 2,00 % (m/m) water in crude petroleum containing less than 0,05 % (m/m) but more than 0,005 % (m/m) of either mercaptan sulfur or sulfide ion sulfur or both. It covers the range 0,02 % (m/m) to 2,00 % (m/m) water in crude petroleum containing less than 0,005 % (m/m) of either mercaptan sulfur or sulfide ion sulfur or both.