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Full Description

1.1 This guide is an introduction to mathematical procedures for correction of interelement (matrix) effects in quantitative X-ray spectrometric analysis.

1.1.1 The procedures described correct only for the interelement effect(s) arising from a homogeneous chemical composition of the specimen. Effects related to either particle size, or mineralogical or metallurgical phases in a specimen are not treated.

1.1.2 These procedures apply to both wavelength and energy-dispersive X-ray spectrometry where the specimen is considered to be infinitely thick, flat, and homogeneous with respect to the depth of penetration of the exciting X-rays (1).2

1.2 This document is not intended to be a comprehensive treatment of the many different techniques employed to compensate for interelement effects. Consult Refs (2-5) for descriptions of other commonly used techniques such as standard addition, internal standardization, etc.

 

Document History

  1. ASTM E1361-02(2021)


    Standard Guide for Correction of Interelement Effects in X-Ray Spectrometric Analysis

    • Most Recent
  2. ASTM E1361-02(2014)e1

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    Standard Guide for Correction of Interelement Effects in X-Ray Spectrometric Analysis

    • Historical Version
  3. ASTM E1361-02(2007)


    Standard Guide for Correction of Interelement Effects in X-Ray Spectrometric Analysis

    • Historical Version
  4. ASTM E1361-02


    Standard Guide for Correction of Interelement Effects in X-Ray Spectrometric Analysis

    • Historical Version
  5. ASTM E1361-90(1999)


    Standard Guide for Correction of Interelement Effects in X-Ray Spectrometric Analysis

    • Historical Version